Articles | Volume 35, issue 3
Ann. Geophys., 35, 677–682, 2017
Ann. Geophys., 35, 677–682, 2017

ANGEO Communicates 23 May 2017

ANGEO Communicates | 23 May 2017

Daytime ozone loss term in the mesopause region

Mikhail Y. Kulikov1, Mikhail V. Belikovich1, Mykhaylo Grygalashvyly2, Gerd R. Sonnemann2,3, Tatiana S. Ermakova1, Anton A. Nechaev1, and Alexander M. Feigin1 Mikhail Y. Kulikov et al.
  • 1Institute of Applied Physics of the Russian Academy of Sciences, 46 Ulyanov Str., 603950 Nizhny Novgorod, Russia
  • 2Leibniz Institute of Atmospheric Physics at the University of Rostock in Kühlungsborn, Schloss-Str. 6, 18225 Ostseebad Kühlungsborn, Germany
  • 3Max Planck Institute for Solar System Research, Max-Planck-Str. 2, 37191 Katlenburg-Lindau, Germany

Abstract. For the retrieval of atomic oxygen via ozone observations in the extended mesopause region under sunlight conditions, two assumptions are used: first, the photochemical equilibrium of ozone and, second, that the ozone losses are dominated by ozone's dissociation from solar UV radiation, silently ignoring the O3 destruction by atomic hydrogen. We verify both by 3-D modeling. We found that ozone approaches photochemical equilibrium at 75–100 km for daytime conditions. Hence, the first assumption is valid. However, the reaction of ozone with atomic hydrogen was found to be an important loss process and should not be omitted in retrieving atomic oxygen.