<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD Journal Publishing DTD v3.0 20080202//EN" "https://jats.nlm.nih.gov/nlm-dtd/publishing/3.0/journalpublishing3.dtd">
<article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" article-type="research-article" dtd-version="3.0" xml:lang="en">
<front>
<journal-meta>
<journal-id journal-id-type="publisher">ANGEO</journal-id>
<journal-title-group>
<journal-title>Annales Geophysicae</journal-title>
<abbrev-journal-title abbrev-type="publisher">ANGEO</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">Ann. Geophys.</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1432-0576</issn>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/angeo-32-207-2014</article-id>
<title-group>
<article-title>Influence of water vapour on the height distribution of positive ions, effective recombination coefficient and ionisation balance in the quiet lower ionosphere</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Barabash</surname>
<given-names>V.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Osepian</surname>
<given-names>A.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Dalin</surname>
<given-names>P.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Luleå University of Technology, Rymdcampus 1, 981 92 Kiruna, Sweden</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Polar Geophysical Institute, Halturina 15, 183 023 Murmansk, Russia</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Swedish Institute of Space Physics, Rymdcampus 1, 981 92 Kiruna, Sweden</addr-line>
</aff>
<pub-date pub-type="epub">
<day>11</day>
<month>03</month>
<year>2014</year>
</pub-date>
<volume>32</volume>
<issue>3</issue>
<fpage>207</fpage>
<lpage>222</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2014 V. Barabash et al.</copyright-statement>
<copyright-year>2014</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 3.0 Unported License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by/3.0/">https://creativecommons.org/licenses/by/3.0/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://angeo.copernicus.org/articles/32/207/2014/angeo-32-207-2014.html">This article is available from https://angeo.copernicus.org/articles/32/207/2014/angeo-32-207-2014.html</self-uri>
<self-uri xlink:href="https://angeo.copernicus.org/articles/32/207/2014/angeo-32-207-2014.pdf">The full text article is available as a PDF file from https://angeo.copernicus.org/articles/32/207/2014/angeo-32-207-2014.pdf</self-uri>
<abstract>
<p>Mesospheric water vapour concentration effects on the ion composition and
electron density in the lower ionosphere under quiet geophysical conditions
were examined. Water vapour is an important compound in the mesosphere and
the lower thermosphere that affects ion composition due to hydrogen radical
production and consequently modifies the electron number density. Recent
lower-ionosphere investigations have primarily concentrated on the
geomagnetic disturbance periods. Meanwhile, studies on the electron density
under quiet conditions are quite rare. The goal of this study is to
contribute to a better understanding of the ionospheric parameter responses
to water vapour variability in the quiet lower ionosphere. By applying a
numerical D region ion chemistry model, we evaluated efficiencies for the
channels forming hydrated cluster ions from the NO&lt;sup&gt;+&lt;/sup&gt; and O&lt;sub&gt;2&lt;/sub&gt;&lt;sup&gt;+&lt;/sup&gt;
primary ions (i.e. NO&lt;sup&gt;+&lt;/sup&gt;.H&lt;sub&gt;2&lt;/sub&gt;O and O&lt;sub&gt;2&lt;/sub&gt;&lt;sup&gt;+&lt;/sup&gt;.H&lt;sub&gt;2&lt;/sub&gt;O,
respectively), and the channel forming H&lt;sup&gt;+&lt;/sup&gt;(H&lt;sub&gt;2&lt;/sub&gt;O)&lt;sub&gt;&lt;i&gt;n&lt;/i&gt;&lt;/sub&gt; proton
hydrates from water clusters at different altitudes using profiles with low
and high water vapour concentrations. Profiles for positive ions, effective
recombination coefficients and electrons were modelled for three particular
cases using electron density measurements obtained during rocket campaigns.
It was found that the water vapour concentration variations in the mesosphere
affect the position of both the Cl&lt;sub&gt;2&lt;/sub&gt;&lt;sup&gt;+&lt;/sup&gt; proton hydrate layer upper
border, comprising the NO&lt;sup&gt;+&lt;/sup&gt;(H&lt;sub&gt;2&lt;/sub&gt;O)&lt;sub&gt;&lt;i&gt;n&lt;/i&gt;&lt;/sub&gt; and
O&lt;sub&gt;2&lt;/sub&gt;&lt;sup&gt;+&lt;/sup&gt;(H&lt;sub&gt;2&lt;/sub&gt;O)&lt;sub&gt;&lt;i&gt;n&lt;/i&gt;&lt;/sub&gt; hydrated cluster ions, and the
Cl&lt;sub&gt;1&lt;/sub&gt;&lt;sup&gt;+&lt;/sup&gt; hydrate cluster layer lower border, comprising the
H&lt;sup&gt;+&lt;/sup&gt;(H&lt;sub&gt;2&lt;/sub&gt;O)&lt;sub&gt;&lt;i&gt;n&lt;/i&gt;&lt;/sub&gt; pure proton hydrates, as well as the numerical
cluster densities. The water variations caused large changes in the effective
recombination coefficient and electron density between altitudes of 75 and
87 km. However, the effective recombination coefficient, &amp;alpha;&lt;sub&gt;eff&lt;/sub&gt;, and electron number density did not respond even to large
water vapour concentration variations occurring at other altitudes in the
mesosphere. We determined the water vapour concentration upper limit at
altitudes between 75 and 87 km, beyond which the water vapour concentration
ceases to influence the numerical densities of Cl&lt;sub&gt;2&lt;/sub&gt;&lt;sup&gt;+&lt;/sup&gt; and Cl&lt;sub&gt;1&lt;/sub&gt;&lt;sup&gt;+&lt;/sup&gt;,
the effective recombination coefficient and the electron number density
in the summer ionosphere. This water vapour concentration limit corresponds
to values found in the H&lt;sub&gt;2&lt;/sub&gt;O-1 profile that was observed in the summer
mesosphere by the Upper Atmosphere Research Satellite (UARS). The electron density modelled using the
H&lt;sub&gt;2&lt;/sub&gt;O-1 profile agreed well with the electron density measured in the
summer ionosphere when the measured profiles did not have sharp gradients.
For sharp gradients in electron and positive ion number densities, a water
profile that can reproduce the characteristic behaviour of the ionospheric
parameters should have an inhomogeneous height distribution of water vapour.</p>
</abstract>
<counts><page-count count="16"/></counts>
</article-meta>
</front>
<body/>
<back>
<ref-list>
<title>References</title>
<ref id="ref1">
<label>1</label><mixed-citation publication-type="other" xlink:type="simple">Arnold, F.: The middle ionized component, Proc. ESA Symposium on rocket and balloon programmers, Boumemouth, 1980.</mixed-citation>
</ref>
<ref id="ref2">
<label>2</label><mixed-citation publication-type="other" xlink:type="simple">Arnold, F. and Krankowsky, D. F.: Negative ions in the lower ionosphere. A comparison of a model computation and mass-spectrometer measurements, J. Atmos. Terr. Phys., 33, 1693–1702, 1971.</mixed-citation>
</ref>
<ref id="ref3">
<label>3</label><mixed-citation publication-type="other" xlink:type="simple">Albritton, D. L.: Ion-neutral reaction-rate constants measured in flow reactions through 1977, Atom. Data Nucl., 22, 1–101, 1978.</mixed-citation>
</ref>
<ref id="ref4">
<label>4</label><mixed-citation publication-type="other" xlink:type="simple">Barabash, V., Osepian, A., Dalin, P., and Kirkwood, S.: Electron density profiles in the quiet lower ionosphere based on the results of modeling and experimental data, Ann. Geophys., 30, 1345–1360, &lt;a href=&quot;http://dx.doi.org/10.5194/angeo-30-1345-2012&quot;&gt;https://doi.org/10.5194/angeo-30-1345-2012&lt;/a&gt;, 2012.</mixed-citation>
</ref>
<ref id="ref5">
<label>5</label><mixed-citation publication-type="other" xlink:type="simple">Brasseur, G. and Salomon, S.: Aeronomy of the Middle Atmosphere, 2nd Edn., D. Reidel Publishing Company, Dorhrecht, Holland, 1986.</mixed-citation>
</ref>
<ref id="ref6">
<label>6</label><mixed-citation publication-type="other" xlink:type="simple">Brekke, A., Holt, O., Dickinson, P. H. G., Friedrich, M., Hansen, T., Stauning, P., and Thrane, E. V.: Development of D region electron and ion densities under various auroral conditions during the Energy Budget Campaign (EBC), J. Atmos. Terr. Phys., 47, 101–121, 1985.</mixed-citation>
</ref>
<ref id="ref7">
<label>7</label><mixed-citation publication-type="other" xlink:type="simple">Chakrabarty, D. K., Chakrabarty, P., and Witt, G.: An attempt to identify the obscured paths of water positive ions build-up in the D region, J. Atmos. Terr. Phys., 40, 437–442, 1978.</mixed-citation>
</ref>
<ref id="ref8">
<label>8</label><mixed-citation publication-type="other" xlink:type="simple">Cosby, P. C., Moseley, J. T., and Peterson, J. R.: Photodissociation spectroscopy of O&lt;sub&gt;3&lt;/sub&gt;&lt;sup&gt;-&lt;/sup&gt;, J. Chem. Phys., 70, 2771–2778, 1978.</mixed-citation>
</ref>
<ref id="ref9">
<label>9</label><mixed-citation publication-type="other" xlink:type="simple">Danilov, A. D. and Simonov, A. G.: A simplified model of the D region, Geomagn, Aeronomy, 1981.</mixed-citation>
</ref>
<ref id="ref10">
<label>10</label><mixed-citation publication-type="other" xlink:type="simple">Danilov, A. D. and Smirnova, N. V.: Ion composition and photochemistry of the lower thermosphere. 2. Ion composition of the D- and E-regions, Geomagn. Aeron., 33, 120–133, 1993.</mixed-citation>
</ref>
<ref id="ref11">
<label>11</label><mixed-citation publication-type="other" xlink:type="simple">Danilov, A. D. and Smirnova, N. V.: Improving the 75 to 300 km ion composition model of the IRI, Adv. Space Res., 15, 171–178, &lt;a href=&quot;http://dx.doi.org/10.1016/S0273-1177(99)80044-1&quot;&gt;https://doi.org/10.1016/S0273-1177(99)80044-1&lt;/a&gt;, 1994.</mixed-citation>
</ref>
<ref id="ref12">
<label>12</label><mixed-citation publication-type="other" xlink:type="simple">Danilov, A. D. and Smirnova, N. V.: Comparison of the mid-latitude model with low-latitude ion composition data, Adv. Space Res., 31, 687–696, 2003.</mixed-citation>
</ref>
<ref id="ref13">
<label>13</label><mixed-citation publication-type="other" xlink:type="simple">Danilov, A. D. and Yaichnikov, A. P.: A new model of the ion composition at 75 to 1000 km for IRI, Adv. Space Res., 5, 75–79, 1985.</mixed-citation>
</ref>
<ref id="ref14">
<label>14</label><mixed-citation publication-type="other" xlink:type="simple">Derblom, H. and Laddel, L.: D region parameters at high latitudes obtained from rocket experiments, J. Atmos. Terr. Phys., 35, 12, 2123–2130, 1973.</mixed-citation>
</ref>
<ref id="ref15">
<label>15</label><mixed-citation publication-type="other" xlink:type="simple">Dunkin, D. B., Fehsenfeld, F. C., Schmelrekopf, A. L., and Ferguson, E. E.: Three-body association reactions of NO&lt;sup&gt;+&lt;/sup&gt; with O&lt;sub&gt;2&lt;/sub&gt;, N&lt;sub&gt;2&lt;/sub&gt; and CO&lt;sub&gt;2&lt;/sub&gt;, J. Chem. Phys., 54, 3817–3822, 1971.</mixed-citation>
</ref>
<ref id="ref16">
<label>16</label><mixed-citation publication-type="other" xlink:type="simple">Fehsenfeld, F. C. and Fergusson, E. E.: Origin of water cluster ions in the D region, J. Geophys. Res., 74, 2217–2222, 1969.</mixed-citation>
</ref>
<ref id="ref17">
<label>17</label><mixed-citation publication-type="other" xlink:type="simple">Fehsenfeld, F. C. and Fergusson, E.: Laboratory studies of negative ion reactions with atmosphere trace constituents. Origin of water cluster ions in the D region, J. Chem., Phys., 61, 3181–3193, 1974.</mixed-citation>
</ref>
<ref id="ref18">
<label>18</label><mixed-citation publication-type="other" xlink:type="simple">Ferguson, E. E.: D region ion chemistry, Rev. Geophys. Space Phys., 9, 997–1008, 1971a.</mixed-citation>
</ref>
<ref id="ref19">
<label>19</label><mixed-citation publication-type="other" xlink:type="simple">Ferguson, E. E.: Laboratory measurements of D region ion-molecule reactions, in Mesospheric Models and Related Experiments, edited by: Flocco, G., Reidel Dordrecht, 188–197, 1971b.</mixed-citation>
</ref>
<ref id="ref20">
<label>20</label><mixed-citation publication-type="other" xlink:type="simple">Ferguson, E. E.: Laboratory measurements of ionospheric ion-molecule reaction rates, Rev. Geophys. Space Phys., 12, 703–713, 1974.</mixed-citation>
</ref>
<ref id="ref21">
<label>21</label><mixed-citation publication-type="other" xlink:type="simple">Ferguson, E. E.: D region ion chemistry, Rev. Geophys. Space Phys., 9, 997–1008, 1976.</mixed-citation>
</ref>
<ref id="ref22">
<label>22</label><mixed-citation publication-type="other" xlink:type="simple">Fritzenwallner, J. and Kopp, E.: Model calculations of the negative ion chemistry in the mesosphere with special emphasis on the chlorine species and the formation of cluster ions, Adv. Space Res., 21, 891–894, 1998.</mixed-citation>
</ref>
<ref id="ref23">
<label>23</label><mixed-citation publication-type="other" xlink:type="simple">Funke, B., Baumgaertner, A., Calisto, M., Egorova, T., Jackman, C. H., Kieser, J., Krivolutsky, A., López-Puertas, M., Marsh, D. R., Reddmann, T., Rozanov, E., Salmi, S.-M., Sinnhuber, M., Stiller, G. P., Verronen, P. T., Versick, S., von Clarmann, T., Vyushkova, T. Y., Wieters, N., and Wissing, J. M.: Composition changes after the &quot;Halloween&quot; solar proton event: the High Energy Particle Precipitation in the Atmosphere (HEPPA) model versus MIPAS data intercomparison study, Atmos. Chem. Phys., 11, 9089–9139, &lt;a href=&quot;http://dx.doi.org/10.5194/acp-11-9089-2011&quot;&gt;https://doi.org/10.5194/acp-11-9089-2011&lt;/a&gt;, 2011.</mixed-citation>
</ref>
<ref id="ref24">
<label>24</label><mixed-citation publication-type="other" xlink:type="simple">Gabriel, A., Körnich, H., Lossow, S., Peter, D. H., Urban, J., and Murtagh, D.: Zonal asymmetries in middle atmospheric ozone and water vapour derived from Odin satellite data 2001–2010, Atmos. Chem. Phys., 11, 9865–9885, 2011.</mixed-citation>
</ref>
<ref id="ref25">
<label>25</label><mixed-citation publication-type="other" xlink:type="simple">Grygalashvyly, M., Sonnemann, G. R., and Hartogh, P.: Long-term behavior of the concentration of the minor constituents in the mesosphere – a model study, Atmos. Chem. Phys., 9, 2779–2792, &lt;a href=&quot;http://dx.doi.org/10.5194/acp-9-2779-2009&quot;&gt;https://doi.org/10.5194/acp-9-2779-2009&lt;/a&gt;, 2009.</mixed-citation>
</ref>
<ref id="ref26">
<label>26</label><mixed-citation publication-type="other" xlink:type="simple">Gumbel, J. and Witt, G.: Cluster ions and ice particle nucleation: Positive feedback at the summer mesopause, J. Geophys. Res. Lett., 29, 29.1–29.4, &lt;a href=&quot;http://dx.doi.org/10.1029/2002GL015146&quot;&gt;https://doi.org/10.1029/2002GL015146&lt;/a&gt;, 2002.</mixed-citation>
</ref>
<ref id="ref27">
<label>27</label><mixed-citation publication-type="other" xlink:type="simple">Hartogh, P., Sonnermann, G. R., Grygalashvily, M., Li Song, Berger, U., and Lübken, F. J.: Water vapour measurements at ALOMAR over a solar cycle compared with model calculations by LIMA, J. Geophys. Res, 115, D00117, &lt;a href=&quot;http://dx.doi.org/10.1029/2009JD012364&quot;&gt;https://doi.org/10.1029/2009JD012364&lt;/a&gt;, 2010.</mixed-citation>
</ref>
<ref id="ref28">
<label>28</label><mixed-citation publication-type="other" xlink:type="simple">Haug, A. and Landmark, B.: A two-ions model of electron-ion recombination in the D region, J. Atmos. Terr. Phys., 32, 405–407, &lt;a href=&quot;http://dx.doi.org/10.1016/0021-9169(70)90012-7&quot;&gt;https://doi.org/10.1016/0021-9169(70)90012-7&lt;/a&gt;, 1970.</mixed-citation>
</ref>
<ref id="ref29">
<label>29</label><mixed-citation publication-type="other" xlink:type="simple">Hedin, A. E.: Extension of the MSIS thermospheric model into the middle and lower atmosphere, J. Geophys. Res. 96, 1159–1172, 1991.</mixed-citation>
</ref>
<ref id="ref30">
<label>30</label><mixed-citation publication-type="other" xlink:type="simple">Hervig, M. and Siskind, D.: Decadal and inter-hemispheric variability in polar mesospheric clouds, water vapour, and temperature, J. Atmos. Terr. Phys., 68, 30–41, 2006.</mixed-citation>
</ref>
<ref id="ref31">
<label>31</label><mixed-citation publication-type="other" xlink:type="simple">Hodges, R. V., Lee, L. C., and Moseley, J. T.: Photodissociation and photodetachment of molecular negative ions, J. Chem. Phys., 72, 2998–3000, 1980.</mixed-citation>
</ref>
<ref id="ref32">
<label>32</label><mixed-citation publication-type="other" xlink:type="simple">Jackman, C. H. and Meade, P. E.: Effect of solar proton events in 1978 and 1979 on the odd nitrogen abundance in the middle atmosphere, J. Geophys. Res., 93, 7984–7090, 1988.</mixed-citation>
</ref>
<ref id="ref33">
<label>33</label><mixed-citation publication-type="other" xlink:type="simple">Jackman, C. H., Cerniglia, M. C., Nielsen, J. E., Allen, D. J., Zawodny, J. M., McPeters, R. D., Douglass, A. R., Rosenfield, J. E., and Rood, R. B.: 2D and 3D model simulations, measurements, and interpretation of the influence of the October 1989 solar proton events in the middle atmosphere, J. Geophys., Res., 100, 11641–11660, 1995.</mixed-citation>
</ref>
<ref id="ref34">
<label>34</label><mixed-citation publication-type="other" xlink:type="simple">Jackman, C. H., McPeters, R. D., Lanow, G. J., Fleming, E. L., Praderas, C. J., and Russel, M.: Northern hemisphere atmospheric effects due to the July 2000 solar proton event, Geophys. Res. Lett., 28, 2883–2886, 2001.</mixed-citation>
</ref>
<ref id="ref35">
<label>35</label><mixed-citation publication-type="other" xlink:type="simple">Jackman, C. H., DeLand, M. T., Labow, G. J., Fleming, E. L., Weisentein, D. K., Ko, M. K. W., Sinnhuber, M., Anderson, J., and Russell, J. M.: The influence of the several very large solar proton events in years 2000–2003 on the neutral middle atmosphere, J. Adv. Space Res., 35, 445–450, 2005.</mixed-citation>
</ref>
<ref id="ref36">
<label>36</label><mixed-citation publication-type="other" xlink:type="simple">Johannessen, A. and Krankowsky, D.: Positive-ion composition measurement in the upper mesosphere and lower thermosphere at high latitudes during summer, J. Geophys. Res., 77, 2888–2901, 1972.</mixed-citation>
</ref>
<ref id="ref37">
<label>37</label><mixed-citation publication-type="other" xlink:type="simple">Kazil, J., Kopp, E., Chabrillat, S., and Bishop, J.: The University of Bern Atmospheric Ion Model: Time dependent modelling of the ions in the mesosphere and lower thermosphere, J. Geophys. Res., 18, 4432, &lt;a href=&quot;http://dx.doi.org/10.1029/2002JD003024&quot;&gt;https://doi.org/10.1029/2002JD003024&lt;/a&gt;, 2003.</mixed-citation>
</ref>
<ref id="ref38">
<label>38</label><mixed-citation publication-type="other" xlink:type="simple">Kirkwood, S., Osepian, A., and Smirnova, N.: Quantitative description of electron precipitation during auroral absorption events in the morning and around noon local time sectors, J. Atmos. Sol.-Terr. Phys., 63, 1907–1921, 2001.</mixed-citation>
</ref>
<ref id="ref39">
<label>39</label><mixed-citation publication-type="other" xlink:type="simple">Kopp, E. and Herrmann, U.: Ion composition in the lower ionosphere, Ann. Geophys., 2, 84–94, 1984.</mixed-citation>
</ref>
<ref id="ref40">
<label>40</label><mixed-citation publication-type="other" xlink:type="simple">Kopp, E., Eberhardt, P., and Hermann, U.: Summer daytime positive ion composition in the D region above Wallop Island, in COSPAR: Space Research, Vol. XVIII, edited by: Mycroft, M. J. and Stickland, A. C., 245–248, Pergamon, New York, 1978.</mixed-citation>
</ref>
<ref id="ref41">
<label>41</label><mixed-citation publication-type="other" xlink:type="simple">Kopp, E., Eberhardt, P., Hermann, U., and Björn, L. G.: Positive ion composition of the high latitude summer D region with noctilucent clouds, J. Geophys. Res., 90, 148–227, 1985.</mixed-citation>
</ref>
<ref id="ref42">
<label>42</label><mixed-citation publication-type="other" xlink:type="simple">Krankowsky, D., Lämmerzahl, P., Götzelmann, A.: Positive ion composition in the lower ionosphere at high latitudes during MAP/WINE, J. Atmos. Terr. Phys., 49, 809–818, 1987.</mixed-citation>
</ref>
<ref id="ref43">
<label>43</label><mixed-citation publication-type="other" xlink:type="simple">Kull, A., Kopp, E., Granier, C., and Brasseur, G.: Ions and electrons of the lower-latitude D region, J. Geophys. Res.,102, 9705–9716, 1997.</mixed-citation>
</ref>
<ref id="ref44">
<label>44</label><mixed-citation publication-type="other" xlink:type="simple">Lopez-Puertas, M., Funke, B., Gil-Lopez, S., von Clarmann, T., Stiller, G. P., Höpfner, M., Kellmann, S., Mengistu Tsidu, G., Fischer, H., and Jackman, C. H.: HNO&lt;sub&gt;3&lt;/sub&gt;, N&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;5&lt;/sub&gt; and ClONO&lt;sub&gt;2&lt;/sub&gt; enhancements after the October–November 2003 solar proton event, J. Geophys. Res., 110, AOS44, &lt;a href=&quot;http://dx.doi.org/10.1029/2005JA011051&quot;&gt;https://doi.org/10.1029/2005JA011051&lt;/a&gt;, 2005.</mixed-citation>
</ref>
<ref id="ref45">
<label>45</label><mixed-citation publication-type="other" xlink:type="simple">Lossow, S., Joachim, U., Eriksson, P., Murtagh, D., and Gumbel, D.: Critical parameters for the retrieval of mesospheric water vapour and temperature from Odin/SMR limb measurements at 557 GHz; Advances in Space Research, COSPAR, Elsevier Ltd, &lt;a href=&quot;http://dx.doi.org/10.1016/j.asr.2007.05.026&quot;&gt;https://doi.org/10.1016/j.asr.2007.05.026&lt;/a&gt;, 2007.</mixed-citation>
</ref>
<ref id="ref46">
<label>46</label><mixed-citation publication-type="other" xlink:type="simple">Mitra, A. P. and Rowe, J. N.: Ionospheric effects of solar flares-IV, changes in D region ion chemistry during solar flares, J. Atmos., Terr. Phys., 34, 795–806, 1972.</mixed-citation>
</ref>
<ref id="ref47">
<label>47</label><mixed-citation publication-type="other" xlink:type="simple">Nacisi, R. S., Bailej, A. D., Della Lucca, L., Sherman, C., and Thomas, D. M.: Mass spectrometric measurements of negative ions in the D-e and lower E regions, J. Atmos. Terr. Phys., 33, 1147–1159, 1971.</mixed-citation>
</ref>
<ref id="ref48">
<label>48</label><mixed-citation publication-type="other" xlink:type="simple">Ogawa, T. and Shimazaki, T.: Diurnal variations of odd nitrogen and ionic densities in the mesosphere and lower thermosphere: simultaneous solution of photochemical-diffusive equations, J. Geophys. Res., 80, 3945–3960, 1975.</mixed-citation>
</ref>
<ref id="ref49">
<label>49</label><mixed-citation publication-type="other" xlink:type="simple">Osepian, A., Tereschenko, V., Dalin, P., and Kirkwood, S.: The role of atomic oxygen concentration in the ionization balance of the lower ionosphere during solar proton events, Ann. Geophys., 26, 131–143, &lt;a href=&quot;http://dx.doi.org/10.5194/angeo-26-131-2008&quot;&gt;https://doi.org/10.5194/angeo-26-131-2008&lt;/a&gt;, 2008.</mixed-citation>
</ref>
<ref id="ref50">
<label>50</label><mixed-citation publication-type="other" xlink:type="simple">Osepian, A., Kirkwood, S., and Dalin, P.: Influence of ozone concentration on the lower ionosphere- modelling and measurements during the 29–30 October 2003 solar proton event, Ann. Geophys., 27, 577–589, 2009a.</mixed-citation>
</ref>
<ref id="ref51">
<label>51</label><mixed-citation publication-type="other" xlink:type="simple">Osepian, A., Kirkwood, S., Dalin, P., and Tereschenko, V.: D-region electron density and effective recombination coefficients during twilight – experimental data and modelling during solar proton events, Ann. Geophys., 27, 3713–3724, &lt;a href=&quot;http://dx.doi.org/10.5194/angeo-27-3713-2009&quot;&gt;https://doi.org/10.5194/angeo-27-3713-2009&lt;/a&gt;, 2009b.</mixed-citation>
</ref>
<ref id="ref52">
<label>52</label><mixed-citation publication-type="other" xlink:type="simple">Picone, J. M., Hedin, A. E., Drob, D. P., and Aikin, A. C.: NRLMSISE-00 empirical model of the atmosphere: Statistical comparisons and scientific issues, J. Geophys. Res., 107, 1468, &lt;a href=&quot;http://dx.doi.org/10.1029/2002JA009430&quot;&gt;https://doi.org/10.1029/2002JA009430&lt;/a&gt;, 2002.</mixed-citation>
</ref>
<ref id="ref53">
<label>53</label><mixed-citation publication-type="other" xlink:type="simple">Reid, G. C.: The production of water cluster positive ions in the quiet daytime D region, Planet. Space Sci., 25, 3, 275–290, 1977.</mixed-citation>
</ref>
<ref id="ref54">
<label>54</label><mixed-citation publication-type="other" xlink:type="simple">Reid, G. C.: Radar observations of negative-ion photodetachment at sunrise in the auroral- zone mesosphere, Planet. Space Sci., 35, 27–37, 1987.</mixed-citation>
</ref>
<ref id="ref55">
<label>55</label><mixed-citation publication-type="other" xlink:type="simple">Rishbeth, H. and Garriott, K.: Introduction to Ionospheric Physics, Academic Press, New York, 1969.</mixed-citation>
</ref>
<ref id="ref56">
<label>56</label><mixed-citation publication-type="other" xlink:type="simple">Rodrigo, R., Lopez-Moreno, J. J., Lopez-Puertas, M., Moreno, F., and Molina, A.: Neutral atmospheric composition between 60 and 220 km: A theoretical model for mid-latitudes, Planet. Space Sci., 34, 723–743, 1986.</mixed-citation>
</ref>
<ref id="ref57">
<label>57</label><mixed-citation publication-type="other" xlink:type="simple">Rohen, G., von Savigny, C., Sinnhuber, M., Liewellyn, E. J., Kauser, J. W., Jackman, C. H., Kallenrode, M. B., Schröter, J., Eichmann, K.-U., Bovensmann, H., and Burrows, J. P.: Ozone depletion during the solar proton events of October/November 2003 as seen by SCIAMACHY, J. Geophys. Res., 110, A09S39, &lt;a href=&quot;http://dx.doi.org/10.1029/2004JAO10984&quot;&gt;https://doi.org/10.1029/2004JAO10984&lt;/a&gt;, 2005.</mixed-citation>
</ref>
<ref id="ref58">
<label>58</label><mixed-citation publication-type="other" xlink:type="simple">Seppala, A., Verronen, P. T., Kyrölä, E., Hassinen, S., Backman, L., Hauchecorne, A., Bertaux, J. L., and Fussen, D.: Solar proton events of Ocotber–November 2003: ozone depletion in the northern hemisphere polar winter as seen by GOMOS/Envisat, J. Geophys. Res. Lett., 31, L19107, &lt;a href=&quot;http://dx.doi.org/10.1029/2004GL021042&quot;&gt;https://doi.org/10.1029/2004GL021042&lt;/a&gt;, 2004.</mixed-citation>
</ref>
<ref id="ref59">
<label>59</label><mixed-citation publication-type="other" xlink:type="simple">Seppala, A., Verronen, P. T., Cilverd, M. A., Randall, C. E., Tamminen, J., Sofieva, V., Beckman, L., and Kyrölä, E.: Arctic and Antarctic polar winter NO&lt;i&gt;&lt;sub&gt;x&lt;/sub&gt;&lt;/i&gt; and energetic particle precipitation in 2002–2006, J. Geopys. Res. Lett., 34, L12810, &lt;a href=&quot;http://dx.doi.org/10.1029/2007GL029733&quot;&gt;https://doi.org/10.1029/2007GL029733&lt;/a&gt;, 2007.</mixed-citation>
</ref>
<ref id="ref60">
<label>60</label><mixed-citation publication-type="other" xlink:type="simple">Shimazaki, T.: The photochemical time constants of minor constituents and their families in the middle atmosphere, J. Atmos. Terr. Phys., 46, 173–191, 1984.</mixed-citation>
</ref>
<ref id="ref61">
<label>61</label><mixed-citation publication-type="other" xlink:type="simple">Shimazaki, T. and Laird, A.: A model calculation of the diurnal variation in minor neutral constituents in the mesosphere and lower thermosphere including transport effects, J. Geophys. Res., 75, 3221–3235, 1970.</mixed-citation>
</ref>
<ref id="ref62">
<label>62</label><mixed-citation publication-type="other" xlink:type="simple">Smirnova, N. V.: Modeling of the ionization-recombination cycle in the D region., Mathematical modelling of the complex processes, Academy of Sciences of the USSR, 22–34, 1982 (in Russian).</mixed-citation>
</ref>
<ref id="ref63">
<label>63</label><mixed-citation publication-type="other" xlink:type="simple">Smirnova, N. V.: The D region during SP-events: the formation rates of the positive cluster ions and negative ions. Ionospheric Research, Academy of Sciences of the USSR, 35, 67–75, 1983a (in Russian).</mixed-citation>
</ref>
<ref id="ref64">
<label>64</label><mixed-citation publication-type="other" xlink:type="simple">Smirnova, N. V.: The model of the ionization-recombination cycle in the D region, PhD thesis, VINITI, Academy of Sciences of the USSR, 1983b (in Russian).</mixed-citation>
</ref>
<ref id="ref65">
<label>65</label><mixed-citation publication-type="other" xlink:type="simple">Smirnova, N. V. and Vlaskov, V. A.: The negative ions in the ionospheric D region, Preprint PGI-82-3-17, Apatity, 46, 1982a (in Russian).</mixed-citation>
</ref>
<ref id="ref66">
<label>66</label><mixed-citation publication-type="other" xlink:type="simple">Smirnova, N. V. and Vlaskov V. A.: Seasonal variations of the ion composition. Mathematical modelling of the complex processes, Academy of Sciences of the USSR, 83–96, 1982b (in Russian).</mixed-citation>
</ref>
<ref id="ref67">
<label>67</label><mixed-citation publication-type="other" xlink:type="simple">Smirnova, N. V. and Vlaskov, V. A.: Aeronomic aspects of the D region winter anomaly, Preprint PGI-8, Apatity, 20, 1983 (in Russian).</mixed-citation>
</ref>
<ref id="ref68">
<label>68</label><mixed-citation publication-type="other" xlink:type="simple">Smirnova, N. V., Ogloblina, O. F., and Vlaskov, V. A.: Modeling of the lower ionosphere, Pageoph., 127, 353–379, 1988.</mixed-citation>
</ref>
<ref id="ref69">
<label>69</label><mixed-citation publication-type="other" xlink:type="simple">Smith, D. and Church, M. J.: Ion-ion reaction rates in the earth&apos;s atmosphere, Planet. Space Sci., 25, 433–439, 1977.</mixed-citation>
</ref>
<ref id="ref70">
<label>70</label><mixed-citation publication-type="other" xlink:type="simple">Smith, D., Adams N. G., and Church M. J.: Mutual neutralization rates of ionospherically important ions, Planet. Space Sci., 24, 697–703, 1976.</mixed-citation>
</ref>
<ref id="ref71">
<label>71</label><mixed-citation publication-type="other" xlink:type="simple">Smith, G. P., Lee, L. C., and Moseley, J. T.: Photodissociation and photodetachement of molecular negative ions. VII. Ions formed in CO&lt;sub&gt;2&lt;/sub&gt;/O&lt;sub&gt;2&lt;/sub&gt;/H&lt;sub&gt;2&lt;/sub&gt;O/ mixtures 3500–5300 Å, J. Chem. Phys., 71, 4024–4031, 1979.</mixed-citation>
</ref>
<ref id="ref72">
<label>72</label><mixed-citation publication-type="other" xlink:type="simple">Singer, W., Latteck, R., Friedrich, M., Wakabayashi, M., and Rapp, M.: Seasonal and solar activity variability of D region electron density at 69° N, J. Atmos. Terr. Phys., 73, 925–935, 2011.</mixed-citation>
</ref>
<ref id="ref73">
<label>73</label><mixed-citation publication-type="other" xlink:type="simple">Solomon, S., Rusch, D. W., Gerard, J. C., Reid, G. C., and Crutsen, P. J.: The effect of particle precipitation events on the neutral and ion chemistry of the middle atmosphere: II. Odd hydrogen, J. Planet. Space Sci., 29, 885–893, 1981.</mixed-citation>
</ref>
<ref id="ref74">
<label>74</label><mixed-citation publication-type="other" xlink:type="simple">Solomon, S., Reid, G. C., Roble, R. G., and Crutsen, P. J.: Phothochemical coupling between the thermosphere and lower atmosphere, 2. D region ion chemistry and the winter anomaly, J. Geophys. Res., 87, 7221–7227, 1982.</mixed-citation>
</ref>
<ref id="ref75">
<label>75</label><mixed-citation publication-type="other" xlink:type="simple">Sonnemann, G. R., Grygalashvily, M., and Berger, U.: Autocatalytic water vapour production as asource of large mixing ratios within the middle to upper mesosphere, J. Geohys. Res., 110, D15303, &lt;a href=&quot;http://dx.doi.org/10.1029/2004JD005593&quot;&gt;https://doi.org/10.1029/2004JD005593&lt;/a&gt;, 2005.</mixed-citation>
</ref>
<ref id="ref76">
<label>76</label><mixed-citation publication-type="other" xlink:type="simple">Sonnemann, G. R., Hartogh, P., Grygalashvily, M., Berger, U., Lübken, F. J., and Grygalashvily, M.: Antropogenic effects on the distribution of minor chemical constituents in the mesosphere/lowe thermosphere – a model study, Adv. Space Res., COSPAR, Elsevier Ltd., &lt;a href=&quot;http://dx.doi.org/10.1016/j.asr.2012.05.016&quot;&gt;https://doi.org/10.1016/j.asr.2012.05.016&lt;/a&gt;, 2012.</mixed-citation>
</ref>
<ref id="ref77">
<label>77</label><mixed-citation publication-type="other" xlink:type="simple">Summers, M. E., Conway, R. R., Englert, C. R., Siskind, D. E., Stevens, M. H., Russel, J. M., Gordley, L. L., and McHugh, M. J.: Discovery of a water vapour layer in the Arctic summer mesosphere: implications for polar mesospheric clouds, Geophys. Res. Lett., 28, 3601–3604, 2001.</mixed-citation>
</ref>
<ref id="ref78">
<label>78</label><mixed-citation publication-type="other" xlink:type="simple">Thomas, L.: NO&lt;sup&gt;+&lt;/sup&gt; and water cluster ions in the D region, J. Atmos. Terr. Phys., 38, 61–67, 1976a.</mixed-citation>
</ref>
<ref id="ref79">
<label>79</label><mixed-citation publication-type="other" xlink:type="simple">Thomas, L.: Mesospheric temperatures and the formation of water cluster ions in the D region, J. Atmos. Terr. Phys., 38, 1235–1250, 1976b.</mixed-citation>
</ref>
<ref id="ref80">
<label>80</label><mixed-citation publication-type="other" xlink:type="simple">Thomas, L. and Bowman, M. R.: A study of pre-sunrise changes in negative ions and electrons in the D-region, Ann. Geophys., 4, 219–228, 1986.</mixed-citation>
</ref>
<ref id="ref81">
<label>81</label><mixed-citation publication-type="other" xlink:type="simple">Turco, R. P. and Sechrist, C. F.: An investigation of the ionospheric D region at sunrise. 2. Estimation of some photodetachment rates, Radio Sci., 7, 717–724, 1972a.</mixed-citation>
</ref>
<ref id="ref82">
<label>82</label><mixed-citation publication-type="other" xlink:type="simple">Turco, R. P. and Sechrist, C. F.: An investigation of the ionospheric D region at sunrise. 1. Time variations of ozone, metastable molecular oxygen and atomic oxygen, Radio Sci., 7, 703–716, 1972b.</mixed-citation>
</ref>
<ref id="ref83">
<label>83</label><mixed-citation publication-type="other" xlink:type="simple">Turunen, E., Matveinen, H., and Ranta, H.: Sodankyla Ion Chemistry (SCI) Model, Sodankyla Geophysical Observatory Report, No. 49, Finland, 1992.</mixed-citation>
</ref>
<ref id="ref84">
<label>84</label><mixed-citation publication-type="other" xlink:type="simple">Verronen, P. T. and Lehmann, R.: Analysis and parameterisation of ionic reactions affecting middle atmospheric HO&lt;i&gt;&lt;sub&gt;x&lt;/sub&gt;&lt;/i&gt; and NO&lt;sub&gt;y&lt;/sub&gt; during solar proton events, Ann. Geophys., 31, 909–956, &lt;a href=&quot;http://dx.doi.org/10.5194/angeo-31-909-2013&quot;&gt;https://doi.org/10.5194/angeo-31-909-2013&lt;/a&gt;, 2013.</mixed-citation>
</ref>
<ref id="ref85">
<label>85</label><mixed-citation publication-type="other" xlink:type="simple">Verronen, P. T., Turunen, E., Ulich, Th., and Kyrölä, E.: Modelling the effects of the October 1989 solar proton event on mesospheric odd nitrogen using a detailed ion and neutral chemistry model, Ann. Geophys., 20, 1967–1976, &lt;a href=&quot;http://dx.doi.org/10.5194/angeo-20-1967-2002&quot;&gt;https://doi.org/10.5194/angeo-20-1967-2002&lt;/a&gt;, 2002.</mixed-citation>
</ref>
<ref id="ref86">
<label>86</label><mixed-citation publication-type="other" xlink:type="simple">Verronen, P. T., Seppälä, A., Clilverd, M. A., Rodger, C. J., Kyrölä, E., Enell, C.-F., Ulich, T., and Turunen, E.: Diurnal variation of ozone depletion during the October–November 2003 solar proton events, J. Geophys. Res., 110, A09S32, &lt;a href=&quot;http://dx.doi.org/10.1029/2004JA010932&quot;&gt;https://doi.org/10.1029/2004JA010932&lt;/a&gt;, 2005.</mixed-citation>
</ref>
<ref id="ref87">
<label>87</label><mixed-citation publication-type="other" xlink:type="simple">Verronen, P. T., Seppälä, A., Kyröla, E., Tamminen, J., Pickett, H. M., and Turunen, E.: Production of odd hydrohen in the mesosphere during the January 2005 soplar proton event, Geopyys. Res. Lett., 33, L24811, &lt;a href=&quot;http://dx.doi.org/10.1029/2006GL028115&quot;&gt;https://doi.org/10.1029/2006GL028115&lt;/a&gt;, 2006.</mixed-citation>
</ref>
<ref id="ref88">
<label>88</label><mixed-citation publication-type="other" xlink:type="simple">Verronen, P. T., Funke, B., Lopez-Puertas, M., Stiller, G. B., von Clarmann, T., Glatthor, N., Enell, C.-F., Turunen, E., and Tamminene, J.: About the increase of HNO&lt;sub&gt;3&lt;/sub&gt; in the stratopause region during the Halloween 2003 solar proton event, Geophys. Res. Lett., 35, L20809, &lt;a href=&quot;http://dx.doi.org/10.1029/2008GL035312&quot;&gt;https://doi.org/10.1029/2008GL035312&lt;/a&gt;, 2008.</mixed-citation>
</ref>
<ref id="ref89">
<label>89</label><mixed-citation publication-type="other" xlink:type="simple">Verronen, P. T., Santee, M. L., Manney, G. L., Lehmann, R., Salmi, S. M., and Seppälä, A.: Nitric acid enhancements in the mesosphere during the January 2005 and December 2006 solar proton events, J. Geophys. Res., 116, D17301, &lt;a href=&quot;http://dx.doi.org/10.1029/2011JD016075&quot;&gt;https://doi.org/10.1029/2011JD016075&lt;/a&gt;, 2011.</mixed-citation>
</ref>
<ref id="ref90">
<label>90</label><mixed-citation publication-type="other" xlink:type="simple">Vlaskov, V. A., Osepian, A. P., Churikova, T. V., and Turunen, E.: Electron number densities in the auroral zone. Experiment and model, Geomagnetizm i Aeronomiia, 30, 143–146, 1990 (in Russian).</mixed-citation>
</ref>
<ref id="ref91">
<label>91</label><mixed-citation publication-type="other" xlink:type="simple">Winkler, H., Kazeminejad, S., Sinnhuber, M., Kallenrode, M.-B., and Notholt, J.: Conversion of mesospheric HCl into active chlorine during the solarproton event in July 2000 in the northern polar region, J. Geophys. Res., 114, D00I03, &lt;a href=&quot;http://dx.doi.org/10.1029/2008JD011587&quot;&gt;https://doi.org/10.1029/2008JD011587&lt;/a&gt;, 2009.</mixed-citation>
</ref>
<ref id="ref92">
<label>92</label><mixed-citation publication-type="other" xlink:type="simple">Wisemberg, J. and Kockarts, G.: Negative ion chemistry in the terrestrial D region and signal flow graph theory, J. Geophys. Res., 85, 4642–4652, 1980.</mixed-citation>
</ref>
<ref id="ref93">
<label>93</label><mixed-citation publication-type="other" xlink:type="simple">Zadorozhny, A. M.: Diffusion-photochemical model of minor neutral constituents in the lower ionosphere, Academy of Science of USSR, Novosibirsk, 1982 (in Russian).</mixed-citation>
</ref>
</ref-list>
</back>
</article>